Homoclinic Signatures of Dynamical Localization

It is demonstrated that the oscillations in the width of the momentum distribution of atoms moving in a phase-modulated standing light field, as a function of the modulation amplitude, are correlated with the variation of the chaotic layer width in energy of an underlying effective pendulum. The maximum effect of dynamical localization and the nearly perfect delocalization are associated with the maxima and minima, respectively, of the chaotic layer width. It is also demonstrated that kinetic energy is conserved as an almost adiabatic invariant at the minima of the chaotic layer width, and that the system is accurately described by delta-kicked rotors at the zeros of the Bessel functions J_0 and J_1. Numerical calculations of kinetic energy and Lyapunov exponents confirm all the theoretical predictions.Comment: 7 pages, 4 figures, enlarged versio

A study of the cc-C3HD\mathrm{C_{3}HD}/cc-C3H2\mathrm{C_{3}H_{2}} ratio in low-mass star forming regions

We use the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ to probe the physical parameters of starless and protostellar cores, related to their evolutionary states, and compare it to the $\mathrm{N_{2}H^{+}}$-deuteration in order to study possible differences between the deuteration of C- and N-bearing species. We observed the main species $c$-$\mathrm{C_{3}H_{2}}$, the singly and doubly deuterated species $c$-$\mathrm{C_{3}HD}$ and $c$-$\mathrm{C_{3}D_{2}}$, as well as the isotopologue $c$-$\mathrm{{H^{13}CC_{2}H}}$ toward 10 starless cores and 5 protostars in the Taurus and Perseus Complexes. We examined the correlation between the $N$($c$-$\mathrm{C_{3}HD}$)/$N$($c$-$\mathrm{C_{3}H_{2}}$) ratio and the dust temperature along with the $\mathrm{H_2}$ column density and the CO depletion factor. The resulting $N$($c$-$\mathrm{C_{3}HD}$)/$N$($c$-$\mathrm{C_{3}H_{2}}$) ratio is within the error bars consistent with $10\%$ in all starless cores with detected $c$-$\mathrm{C_{3}HD}$. This also accounts for the protostars except for the source HH211, where we measure a high deuteration level of $23\%$. The deuteration of $\mathrm{N_{2}H^{+}}$ follows the same trend but is considerably higher in the dynamically evolved core L1544. Toward the protostellar cores the coolest objects show the largest deuterium fraction in $c$-$\mathrm{C_{3}H_{2}}$. We show that the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ can trace the early phases of star formation and is comparable to that of $\mathrm{N_{2}H^{+}}$. However, the largest $c$-$\mathrm{C_{3}H_{2}}$ deuteration level is found toward protostellar cores, suggesting that while $c$-$\mathrm{C_{3}H_{2}}$ is mainly frozen onto dust grains in the central regions of starless cores, active deuteration is taking place on ice

Search for grain growth towards the center of L1544

In dense and cold molecular clouds dust grains are surrounded by thick icy mantles. It is however not clear if dust growth and coagulation take place before the switch-on of a protostar. This is an important issue, as the presence of large grains may affect the chemical structure of dense cloud cores, including the dynamically important ionization fraction, and the future evolution of solids in protoplanetary disks. To study this further, we focus on L1544, one of the most centrally concentrated pre-stellar cores on the verge of star formation, and with a well-known physical structure. We observed L1544 at 1.2 and 2 mm using NIKA, a new receiver at the IRAM 30 m telescope, and we used data from the Herschel Space Observatory archive. We find no evidence of grain growth towards the center of L1544 at the available angular resolution. Therefore, we conclude that single dish observations do not allow us to investigate grain growth toward the pre-stellar core L1544 and high sensitivity interferometer observations are needed. We predict that dust grains can grow to 200 $\mu$m in size toward the central ~300 au of L1544. This will imply a dust opacity change by a factor of ~2.5 at 1.2 mm, which can be detected using the Atacama Large Millimeter and submillimeter Array (ALMA) at different wavelengths and with an angular resolution of 2".Comment: 12 pages, 14 figures. Accepted for publication in A&

Development of a work climate scale in emergency health services

An adequate work climate fosters productivity in organizations and increases employee satisfaction. Workers in emergency health services (EHS) have an extremely high degree of responsibility and consequent stress. Therefore, it is essential to foster a good work climate in this context. Despite this, scales with a full study of their psychometric properties (i.e., validity evidence based on test content, internal structure and relations to other variables, and reliability) are not available to measure work climate in EHS specifically. For this reason, our objective was to develop a scale tomeasure the quality of work climates in EHS.We carried out three studies. In Study 1, we used a mixed-method approach to identify the latent conceptual structure of the construct work climate. Thus, we integrated the results found in (a) a previous study, where a content analysis of seven in-depth interviews obtained from EHS professionals in two hospitals in Gibraltar Countryside County was carried out; and (b) the factor analysis of the responses given by 113 EHS professionals from these same centers to 18 items that measured the work climate in health organizations. As a result, we obtained 56 items grouped into four factors (work satisfaction, productivity/achievement of aims, interpersonal relationships, and performance at work). In Study 2, we presented validity evidence based on test content through experts’ judgment. Fourteen experts from the methodology and health fields evaluated the representativeness, utility, and feasibility of each of the 56 items with respect to their factor (theoretical dimension). Forty items met the inclusion criterion, which was to obtain an Osterlind index value greater than or equal to 0.5 in the three aspects assessed. In Study 3, 201 EHS professionals from the same centers completed the resulting 40-item scale. This new instrument produced validity evidence based on the internal structure in a second-order factormodel with four components (RMSEA=0.079, GFI = 0.97, AGFI = 0.97, CFI = 0.97; NFI = 0.95, and NNFI = 0.97); absence of differential Item Functioning (DIF) in 80% of the items; reliability (a = 0.96); and validity evidence based on relations to other variables, specifically the test-criterion relationship (r = 0.680). Finally, we discuss further developments of the instrument and its possible implications for EHS workers.Ministerio de Ciencia e Innovación PSI2011-29587Ministerio de Economía y Competitividad PSI2015-71947-RED

Mesoscopic Hamiltonian for the fluctuations of adsorbed Lennard-Jones liquid films

We use Monte Carlo simulations of a Lennard-Jones fluid adsorbed on a short-range planar wall substrate to study the fluctuations in the thickness of the wetting layer, and we get a quantitative and consistent characterization of their mesoscopic Hamiltonian, H[ξ]. We have observed important finite-size effects, which were hampering the analysis of previous results obtained with smaller systems. The results presented here support an appealing simple functional form for H[ξ], close but not exactly equal to the theoretical nonlocal proposal made on the basis a generic density-functional analysis by Parry and coworkers. We have analyzed systems under different wetting conditions, as a proof of principle for a method that provides a quantitative bridge between the molecular interactions and the phenomenology of wetting films at mesoscopic scalesWe acknowledge the support of the Spanish Ministry of Science and Innovation (Grants No. FIS2010- 22047-C05 and No. FIS2013-47350-C5

Bending modulus of lipid membranes from density correlation functions.

The bending modulus κ quantifies the elasticity of biological membranes in terms of the free energy cost of increasing the membrane corrugation. Molecular dynamics (MD) simulations provide a powerful approach to quantify κ by analyzing the thermal fluctuations of the lipid bilayer. However, existing methods require the identification and filtering of non-mesoscopic fluctuation modes. State of the art methods rely on identifying a smooth surface to describe the membrane shape. These methods introduce uncertainties in calculating κ since they rely on different criteria to select the relevant fluctuation modes. Here, we present a method to compute κ using molecular simulations. Our approach circumvents the need to define a mesoscopic surface or an orientation field for the lipid tails explicitly. The bending and tilt moduli can be extracted from the analysis of the density correlation function (DCF). The method introduced here builds on the Bedeaux and Weeks (BW) theory for the DCF of fluctuating interfaces and on the coupled undulatory (CU) mode introduced by us in previous work. We test the BW-DCF method by computing the elastic properties of lipid membranes with different system sizes (from 500 to 6000 lipid molecules) and using coarse-grained (for POPC and DPPC lipids) and fully atomistic models (for DPPC). Further, we quantify the impact of cholesterol on the bending modulus of DPPC bilayers. We compare our results with bending moduli obtained with X-ray diffraction data and different computer simulation methods

Current sheet bifurcation and collapse in electron magnetohydrodynamics

Inertial effects in nonlinear magnetic reconnection are studied within the context of 2D electron magnetohydrodynamics (EMHD) with resistive and viscous dissipation. Families of nonlinear solutions for relevant current sheet parameters are predicted and confirmed numerically in all regimes of interest. Electron inertia becomes important for current sheet thicknesses $\delta$ below the inertial length $d_{e}$. In this case, in the absence of electron viscosity, the sheet thickness experiences a nonlinear collapse. Viscosity regularizes solutions at small scales. Transition from resistive to viscous regimes shows a nontrivial dependence on resistivity and viscosity, featuring a hysteresis bifurcation. In all accessible regimes, the nonlinear reconnection rate is found to be explicitly independent of the electron inertia and dissipation coefficients.Comment: submitted to publicatio

Synthesis and Characterization of a Gallic Acid Metal Organic Framework for Antitumoral Therapy

Motivation: Nano-Metal Organic Frameworks (n-MOFs) are emerging as promising drug delivery systems in biomedical applications owing to their composition versatility and high porosity [1] The aim of our work was to synthetize an n-MOF comprising Gallic acid (GA), as organic ligand, and Fe III, as coordination cation. The election of the n-MOF components obeys to their physiological properties. Specifically, GA is a natural product belonging to the family of polyphenols, which exert a wide range of biological activities, such as antioxidant and pro-apoptotic activities that may be applied in tumor prevention [2] and antitumoral therapy [3,4], respectively.Methods: The n-MOF comprising GA and Fe(III), GalFe, has been synthetized under gentle conditions (room temperature and aqueous medium) and characterized by UV-Vis spectrometry, FTIR spectroscopy, DLS and electron microscopy. Studies of entrapment efficiency and release profile were performed using a fluorescent marker (rhodamine 6G; R6G) as model cargo.Results: GalFe nanoparticles are spherical, with a mean hydrodynamic diameter of 270 nm and a zeta potential of -22 mV. The FTIR spectrum of GalFe is similar to that of nano-MOF MIL-53, which comprises terephthalic acid and Fe (III), and the characteristic bands of GA are clearly observable in the spectrum. GalFe nanoparticles are stable in water over a wide range of pHs (from pH 4 to 9). At low pH (1-3), nevertheless, most of the hydroxyl groups are protonated, which led to a rapid destabilization and disassembly [5]. The entrapment efficiency of R6G is extremely high (99.9%), and the nanoparticles do not release their cargo after 24 hours of dialysis against water. Conclusions: We have synthetized and characterized an n-MOFS that contains gallic acid as organic ligand. Pro-apoptotic properties of gallic acid convert this new nanomaterial into a promising candidate in antitumoral therapy. An additional layer of complexity was introduced by encapsulating a water-soluble fluorescent marker, giving access to imaging and therapeutic applications